Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
ChemistrySelect 2 巻 11 号
3212-3215 頁
2017-04-13 発行
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| ファイル情報(添付) | |
| タイトル ( eng ) |
Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
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| 作成者 |
Kubo Teruhiko
Kuriki Hitoshi
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| 収録物名 |
ChemistrySelect
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| 巻 | 2 |
| 号 | 11 |
| 開始ページ | 3212 |
| 終了ページ | 3215 |
| 抄録 |
A carbon–carbon triple bond of arynes was found to undergo cyanostannylation with a tin cyanide under CuCN catalysis to afford diverse ortho-cyanoarylstannanes in high yield. The copper catalyst was also effective for alkynylstannylation of arynes, and the resulting alkynylstannylated products were demonstrated to be convertible into biologically active compounds and a dye for dyesensitized solar cell.
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| 著者キーワード |
alkynylstannylation
arynes
copper
cyanostannylation
dye-sensitized solar cells
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| 内容記述 |
This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding and by ACT-C, JST.
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Wiley
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| 発行日 | 2017-04-13 |
| 権利情報 |
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
This is the peer reviewed version of the following article: Hiroto Yoshida, Teruhiko Kubo, Hitoshi Kuriki, Itaru Osaka, Ken Takaki and Yousuke Ooyama, Ligand‐Free Copper‐Catalyzed Cyano‐ and Alkynylstannylation of Arynes, ChemistrySelect, 2017, 2, 3212-3215, which has been published in final form at https://doi.org/10.1002/slct.201700297. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
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| 出版タイプ | Author’s Original（十分な品質であるとして、著者から正式な査読に提出される版） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[ISSN] 2365-6549
[DOI] 10.1002/slct.201700297
[DOI] https://doi.org/10.1002/slct.201700297
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