Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes

ChemistrySelect 2 巻 11 号 3212-3215 頁 2017-04-13 発行
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タイトル ( eng )
Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
作成者
Kubo Teruhiko
Kuriki Hitoshi
収録物名
ChemistrySelect
2
11
開始ページ 3212
終了ページ 3215
抄録
A carbon–carbon triple bond of arynes was found to undergo cyanostannylation with a tin cyanide under CuCN catalysis to afford diverse ortho-cyanoarylstannanes in high yield. The copper catalyst was also effective for alkynylstannylation of arynes, and the resulting alkynylstannylated products were demonstrated to be convertible into biologically active compounds and a dye for dyesensitized solar cell.
著者キーワード
alkynylstannylation
arynes
copper
cyanostannylation
dye-sensitized solar cells
内容記述
This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding and by ACT-C, JST.
言語
英語
資源タイプ 学術雑誌論文
出版者
Wiley
発行日 2017-04-13
権利情報
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
This is the peer reviewed version of the following article: Hiroto Yoshida, Teruhiko Kubo, Hitoshi Kuriki, Itaru Osaka, Ken Takaki and Yousuke Ooyama, Ligand‐Free Copper‐Catalyzed Cyano‐ and Alkynylstannylation of Arynes, ChemistrySelect, 2017, 2, 3212-3215, which has been published in final form at https://doi.org/10.1002/slct.201700297. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
出版タイプ Author’s Original(十分な品質であるとして、著者から正式な査読に提出される版)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 2365-6549
[DOI] 10.1002/slct.201700297
[DOI] https://doi.org/10.1002/slct.201700297