Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
ChemistrySelect Volume 2 Issue 11
Page 3212-3215
published_at 2017-04-13
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| File | |
| Title ( eng ) |
Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
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| Creator |
Kubo Teruhiko
Kuriki Hitoshi
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| Source Title |
ChemistrySelect
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| Volume | 2 |
| Issue | 11 |
| Start Page | 3212 |
| End Page | 3215 |
| Abstract |
A carbon–carbon triple bond of arynes was found to undergo cyanostannylation with a tin cyanide under CuCN catalysis to afford diverse ortho-cyanoarylstannanes in high yield. The copper catalyst was also effective for alkynylstannylation of arynes, and the resulting alkynylstannylated products were demonstrated to be convertible into biologically active compounds and a dye for dyesensitized solar cell.
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| Keywords |
alkynylstannylation
arynes
copper
cyanostannylation
dye-sensitized solar cells
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| Descriptions |
This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding and by ACT-C, JST.
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Wiley
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| Date of Issued | 2017-04-13 |
| Rights |
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
This is the peer reviewed version of the following article: Hiroto Yoshida, Teruhiko Kubo, Hitoshi Kuriki, Itaru Osaka, Ken Takaki and Yousuke Ooyama, Ligand‐Free Copper‐Catalyzed Cyano‐ and Alkynylstannylation of Arynes, ChemistrySelect, 2017, 2, 3212-3215, which has been published in final form at https://doi.org/10.1002/slct.201700297. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 2365-6549
[DOI] 10.1002/slct.201700297
[DOI] https://doi.org/10.1002/slct.201700297
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