Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes
Tetrahedron Letters Volume 42 Issue 52
Page 9211-9214
published_at 2001-12-24
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| File | |
| Title ( eng ) |
Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes
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| Creator |
Sonoda Kentaro
Kousaka Takeshi
Koshoji Go
Shishido Tetsuya
Takehira Katsuomi
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| Source Title |
Tetrahedron Letters
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| Volume | 42 |
| Issue | 52 |
| Start Page | 9211 |
| End Page | 9214 |
| Abstract |
Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.
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| Keywords |
Conjugated dienes
Double silylation
Hydrosilylation
Lanthanide catalyst
Olefins
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier Science Ltd.
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| Date of Issued | 2001-12-24 |
| Rights |
(c) 2001 Elsevier Science Ltd.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[NCID] AA00861801
[ISSN] 0040-4039
[DOI] 10.1016/S0040-4039(01)02027-5
[DOI] http://dx.doi.org/10.1016/S0040-4039(01)02027-5
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