Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes

Tetrahedron Letters Volume 42 Issue 52 Page 9211-9214 published_at 2001-12-24
アクセス数 : 787
ダウンロード数 : 194

今月のアクセス数 : 3
今月のダウンロード数 : 3
File
TetraLett_42_9211_takaki.pdf 531 KB 種類 : fulltext
Title ( eng )
Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes
Creator
Sonoda Kentaro
Kousaka Takeshi
Koshoji Go
Shishido Tetsuya
Takehira Katsuomi
Source Title
Tetrahedron Letters
Volume 42
Issue 52
Start Page 9211
End Page 9214
Abstract
Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.
Keywords
Conjugated dienes
Double silylation
Hydrosilylation
Lanthanide catalyst
Olefins
Language
eng
Resource Type journal article
Publisher
Elsevier Science Ltd.
Date of Issued 2001-12-24
Rights
(c) 2001 Elsevier Science Ltd.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[NCID] AA00861801
[ISSN] 0040-4039
[DOI] 10.1016/S0040-4039(01)02027-5
[DOI] http://dx.doi.org/10.1016/S0040-4039(01)02027-5 isVersionOf