Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand

Chemical Communications Volume 56 Issue 26 Page 3733-3736 published_at 2020-04-04
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Title ( eng )
Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand
Creator
Shimoyama Daisuke
Source Title
Chemical Communications
Volume 56
Issue 26
Start Page 3733
End Page 3736
Abstract
An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.
Descriptions
This work was supported by the Grants-in-Aid for Scientific Research, JSPS KAKENHI Grant JP15H03817, and by the Grants-in-Aid for Scientific Research on Innovative Areas, JSPS KAKENHI Grants JP19H04585 (Coordination Asymmetry). Funding from The Ogasawara Foundation for the Promotion of Science & Engineering, The Futaba Electronics Memorial Foundation, Nippon Sheet Glass Foundation, Iketani Science and Technology Foundation, Takahashi Industrial and Economic Research Foundation, and Fukuoka Naohiko Memorial Foundation is gratefully acknowledged.
Language
eng
Resource Type journal article
Publisher
Royal Society of Chemistry
Date of Issued 2020-04-04
Rights
This is not the published version. Please cite only the published version. この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/D0CC00933D
[DOI] https://doi.org/10.1039/D0CC00933D
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