Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
Chemical Communications Volume 51
Page 9440-9442
published_at 2015-04-14
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| File | |
| Title ( eng ) |
Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
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| Creator |
Hayashi Y.
Ito Y.
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| Source Title |
Chemical Communications
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| Volume | 51 |
| Start Page | 9440 |
| End Page | 9442 |
| Abstract |
Silylstannylation of alkynes and allenes has been found to proceed by three-component coupling using a silylborane and a tin alkoxide in the presence of a Cu(I) catalyst. The regioselectivities are completely inverse to those of the conventional silylstannylation under palladium catalysis.
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Royal Society of Chemistry
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| Date of Issued | 2015-04-14 |
| Rights |
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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| Publish Type | Version of Record |
| Access Rights | open access |
| Source Identifier |
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c5cc01856k
[DOI] https://doi.org/10.1039/c5cc01856k
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