Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide

Chemical Communications Volume 51 Page 9440-9442 published_at 2015-04-14
アクセス数 : 423
ダウンロード数 : 64

今月のアクセス数 : 7
今月のダウンロード数 : 3
File
ChemCommun_51_9440.pdf 2.18 MB 種類 : fulltext
Title ( eng )
Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
Creator
Hayashi Y.
Ito Y.
Source Title
Chemical Communications
Volume 51
Start Page 9440
End Page 9442
Abstract
Silylstannylation of alkynes and allenes has been found to proceed by three-component coupling using a silylborane and a tin alkoxide in the presence of a Cu(I) catalyst. The regioselectivities are completely inverse to those of the conventional silylstannylation under palladium catalysis.
Language
eng
Resource Type journal article
Publisher
Royal Society of Chemistry
Date of Issued 2015-04-14
Rights
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c5cc01856k
[DOI] https://doi.org/10.1039/c5cc01856k