Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
Chemical Communications Volume 51
Page 9440-9442
published_at 2015-04-14
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Title ( eng ) |
Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
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Creator |
Hayashi Y.
Ito Y.
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Source Title |
Chemical Communications
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Volume | 51 |
Start Page | 9440 |
End Page | 9442 |
Abstract |
Silylstannylation of alkynes and allenes has been found to proceed by three-component coupling using a silylborane and a tin alkoxide in the presence of a Cu(I) catalyst. The regioselectivities are completely inverse to those of the conventional silylstannylation under palladium catalysis.
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Language |
eng
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Resource Type | journal article |
Publisher |
Royal Society of Chemistry
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Date of Issued | 2015-04-14 |
Rights |
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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Publish Type | Version of Record |
Access Rights | open access |
Source Identifier |
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c5cc01856k
[DOI] https://doi.org/10.1039/c5cc01856k
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