ゼオライト合成における結晶化調整剤の影響 <ノート>

日本化学会誌 : 化学と工業化学 Volume 1999 Issue 7 Page 487-491 published_at 1999-07-10
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Title ( jpn )
ゼオライト合成における結晶化調整剤の影響 <ノート>
Title ( eng )
Influence of Structure-directing Agent on Zeolite Synthesis <Note>
Creator
Suzuki Atsushi
Wang Zhengbao
Ahn Cheol-Hee
Soga Kazuo
Source Title
日本化学会誌 : 化学と工業化学
Journal of the Chemical Society of Japan : chemistry and industrial chemistry
Volume 1999
Issue 7
Start Page 487
End Page 491
Abstract
To get more information concerning zeolite synthesis in the presence of 1-butanol (n-BuOH), influences of the alkali metal cation and the synthesis conditions on the zeolite synthesis were investigated. It was found that highly crystalline TON (Theta-1), MER (Merlinoite) and LTL (L) type zeolites were synthesized when KOH was employed as an alkali source, whereas MFI (ZSM-5) and MOR (Mordenite)type zeolites for NaOH. Characterization of zeolites obtained was conducted using X-ray diffraction, scanning electron microscopy, FT-IR, thermal analysis, 13C and 27Al MAS NMR. From the results of FT-IR and 13C CP MAS NMR measurements of as-made zeolites, it was concluded that n-BuOH molecules were occluded in the zeolitic pores of TON and MFI type zeolites, while no n-BuOH molecules for MOR, MER and LTL type zeolites.
NDC
Chemistry [ 430 ]
Language
jpn
Resource Type journal article
Publisher
日本化学会
Date of Issued 1999-07-10
Rights
Copyright (c) 1999 The Chemical Society of Japan
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 0369-4577
[NCID] AN00186595
[DOI] 10.1246/nikkashi.1999.487
[DOI] https://doi.org/10.1246/nikkashi.1999.487