ゼオライト合成における結晶化調整剤の影響 <ノート>
日本化学会誌 : 化学と工業化学 Volume 1999 Issue 7
Page 487-491
published_at 1999-07-10
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Title ( jpn ) |
ゼオライト合成における結晶化調整剤の影響 <ノート>
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Title ( eng ) |
Influence of Structure-directing Agent on Zeolite Synthesis <Note>
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Creator |
Suzuki Atsushi
Wang Zhengbao
Ahn Cheol-Hee
Soga Kazuo
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Source Title |
日本化学会誌 : 化学と工業化学
Journal of the Chemical Society of Japan : chemistry and industrial chemistry
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Volume | 1999 |
Issue | 7 |
Start Page | 487 |
End Page | 491 |
Abstract |
To get more information concerning zeolite synthesis in the presence of 1-butanol (n-BuOH), influences of the alkali metal cation and the synthesis conditions on the zeolite synthesis were investigated. It was found that highly crystalline TON (Theta-1), MER (Merlinoite) and LTL (L) type zeolites were synthesized when KOH was employed as an alkali source, whereas MFI (ZSM-5) and MOR (Mordenite)type zeolites for NaOH. Characterization of zeolites obtained was conducted using X-ray diffraction, scanning electron microscopy, FT-IR, thermal analysis, 13C and 27Al MAS NMR. From the results of FT-IR and 13C CP MAS NMR measurements of as-made zeolites, it was concluded that n-BuOH molecules were occluded in the zeolitic pores of TON and MFI type zeolites, while no n-BuOH molecules for MOR, MER and LTL type zeolites.
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NDC |
Chemistry [ 430 ]
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Language |
jpn
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Resource Type | journal article |
Publisher |
日本化学会
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Date of Issued | 1999-07-10 |
Rights |
Copyright (c) 1999 The Chemical Society of Japan
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Publish Type | Version of Record |
Access Rights | open access |
Source Identifier |
[ISSN] 0369-4577
[NCID] AN00186595
[DOI] 10.1246/nikkashi.1999.487
[DOI] https://doi.org/10.1246/nikkashi.1999.487
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