New theory of effective work functions at metal/high-k dielectric interfaces : application to metal/high-k HfO2 and la2O 3 dielectric interfaces

ECS Transactions Volume 2 Issue 1 Page 25-40 published_at 2006
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Title ( eng )
New theory of effective work functions at metal/high-k dielectric interfaces : application to metal/high-k HfO2 and la2O 3 dielectric interfaces
Creator
Shiraishi Kenji
Akasaka Yasushi
Nakaoka Takashi
Ohmori Kenji
Ahmet Parhat
Torii Kazuyoshi
Watanabe Heiji
Chikyow Toyohiro
Nara Yasuo
Iwai Hiroshi
Yamada Keisaku
Source Title
ECS Transactions
Volume 2
Issue 1
Start Page 25
End Page 40
Abstract
We have constructed a universal theory of the work functions at metal/high-k HfO2 and La2O3 dielectric interfaces by introducing a new concept of generalized charge neutrality levels. Our theory systematically reproduces the experimentally observed work functions of various gate metals on Hf-based high-k dielectrics, including the hitherto unpredictable behaviors of the work functions of p-metals. Our new concept provides effective guiding principles to achieving near-bandedge work functions of gate metals. Moreover, we discuss the potential of the new high-k dielectrics of La2O3 based on this new concept.
Language
eng
Resource Type conference paper
Publisher
The Electrochemical Society
Date of Issued 2006
Rights
Copyright (c) 2006 The Electrochemical Society
Publish Type Author’s Original
Access Rights open access
Source Identifier
[DOI] 10.1149/1.2193871
[NCID] BA78566750
[DOI] http://dx.doi.org/10.1149/1.2193871