Electron conductive three-dimensional polymer of cuboidal C60

Physical Review Letters 96 巻 7 号 076602- 頁 2006 発行
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PhysRevLett_96_076602.pdf 530 KB 種類 : 全文
タイトル ( eng )
Electron conductive three-dimensional polymer of cuboidal C60
作成者
Kubo Akira
Kini N. S.
Inoue Toru
Irifune Tetsuo
収録物名
Physical Review Letters
96
7
開始ページ 076602
抄録
Single crystals of three-dimensional (3D) C60 polymer were prepared by the topotactic conversion of two-dimensional (2D) C60 polymer single crystals at a pressure of 15 GPa at 600°C. The x-ray single crystal study revealed that the 3D C60 polymer crystallized in a body centered orthorhombic space group Immm, and spherical C60 monomer units were substantially deformed to rectangular parallelepiped (cuboidal) shapes, each unit being bonded to eight cuboidal C60 neighbors via [3+3] cycloaddition. The 3D C60 polymer was electron conductive, in contrast with the nonconductive behavior of 2D polymers.
NDC分類
物理学 [ 420 ]
言語
英語
資源タイプ 学術雑誌論文
出版者
American Physical Society
発行日 2006
権利情報
Copyright (c) 2006 American Physical Society
出版タイプ Version of Record(出版社版。早期公開を含む)
アクセス権 オープンアクセス
収録物識別子
[NCID] AA00773679
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.96.076602
[DOI] http://dx.doi.org/10.1103/PhysRevLett.96.076602