Electron conductive three-dimensional polymer of cuboidal C60

Physical Review Letters Volume 96 Issue 7 Page 076602- published_at 2006
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Title ( eng )
Electron conductive three-dimensional polymer of cuboidal C60
Creator
Kubo Akira
Kini N. S.
Inoue Toru
Irifune Tetsuo
Source Title
Physical Review Letters
Volume 96
Issue 7
Start Page 076602
Abstract
Single crystals of three-dimensional (3D) C60 polymer were prepared by the topotactic conversion of two-dimensional (2D) C60 polymer single crystals at a pressure of 15 GPa at 600°C. The x-ray single crystal study revealed that the 3D C60 polymer crystallized in a body centered orthorhombic space group Immm, and spherical C60 monomer units were substantially deformed to rectangular parallelepiped (cuboidal) shapes, each unit being bonded to eight cuboidal C60 neighbors via [3+3] cycloaddition. The 3D C60 polymer was electron conductive, in contrast with the nonconductive behavior of 2D polymers.
NDC
Physics [ 420 ]
Language
eng
Resource Type journal article
Publisher
American Physical Society
Date of Issued 2006
Rights
Copyright (c) 2006 American Physical Society
Publish Type Version of Record
Access Rights open access
Source Identifier
[NCID] AA00773679
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.96.076602
[DOI] http://dx.doi.org/10.1103/PhysRevLett.96.076602