Electron conductive three-dimensional polymer of cuboidal C60
Physical Review Letters Volume 96 Issue 7
Page 076602-
published_at 2006
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| File | |
| Title ( eng ) |
Electron conductive three-dimensional polymer of cuboidal C60
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| Creator |
Kubo Akira
Kini N. S.
Inoue Toru
Irifune Tetsuo
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| Source Title |
Physical Review Letters
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| Volume | 96 |
| Issue | 7 |
| Start Page | 076602 |
| Abstract |
Single crystals of three-dimensional (3D) C60 polymer were prepared by the topotactic conversion of two-dimensional (2D) C60 polymer single crystals at a pressure of 15 GPa at 600°C. The x-ray single crystal study revealed that the 3D C60 polymer crystallized in a body centered orthorhombic space group Immm, and spherical C60 monomer units were substantially deformed to rectangular parallelepiped (cuboidal) shapes, each unit being bonded to eight cuboidal C60 neighbors via [3+3] cycloaddition. The 3D C60 polymer was electron conductive, in contrast with the nonconductive behavior of 2D polymers.
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| NDC |
Physics [ 420 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
American Physical Society
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| Date of Issued | 2006 |
| Rights |
Copyright (c) 2006 American Physical Society
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| Publish Type | Version of Record |
| Access Rights | open access |
| Source Identifier |
[NCID] AA00773679
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.96.076602
[DOI] http://dx.doi.org/10.1103/PhysRevLett.96.076602
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