Infrared photodissociation spectra and solvation structures of Cu+(H2O)n (n = 1-4)
Chemical Physics Letters Volume 427 Issue 1–3
Page 24-28
published_at 2006-08-18
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| File | |
| Title ( eng ) |
Infrared photodissociation spectra and solvation structures of Cu+(H2O)n (n = 1-4)
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| Creator |
Iino Takuro
Ohashi Kazuhiko
Mune Yutaka
Judai Ken
Nishi Nobuyuki
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| Source Title |
Chemical Physics Letters
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| Volume | 427 |
| Issue | 1–3 |
| Start Page | 24 |
| End Page | 28 |
| Abstract |
Coordination and solvation structures of the Cu+(H2O)n ions with n = 1–4 are studied by infrared photodissociation spectroscopy and density functional theory calculations. Hydrogen bonding between H2O molecules is detected in Cu+(H2O)3 and Cu+(H2O)4 through a characteristic change in the position and intensity of OH-stretching transitions. The third and fourth waters prefer hydrogen-bonding sites in the second solvation shell rather than direct coordination to Cu+. The infrared spectroscopy verifies that the gas-phase coordination number of Cu+ in Cu+(H2O)n is two and the resulting linearly coordinated structure acts as the core of further solvation processes.
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| Descriptions |
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2006.06.036
This work was supported in part by “Nanotechnology Support Project” and Grant-in-Aid for Scientific Research (No. 17550014) of the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B.V.
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| Date of Issued | 2006-08-18 |
| Rights |
(c) 2006 Elsevier B.V. All rights reserved.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2006.06.036
[DOI] http://doi.org/10.1016/j.cplett.2006.06.036
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