Infrared photodissociation spectra and solvation structures of Cu+(H2O)n (n = 1-4)
Chemical Physics Letters 427 巻 1–3 号
24-28 頁
2006-08-18 発行
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| ファイル情報(添付) | |
| タイトル ( eng ) |
Infrared photodissociation spectra and solvation structures of Cu+(H2O)n (n = 1-4)
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| 作成者 |
Iino Takuro
Ohashi Kazuhiko
Mune Yutaka
Judai Ken
Nishi Nobuyuki
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| 収録物名 |
Chemical Physics Letters
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| 巻 | 427 |
| 号 | 1–3 |
| 開始ページ | 24 |
| 終了ページ | 28 |
| 抄録 |
Coordination and solvation structures of the Cu+(H2O)n ions with n = 1–4 are studied by infrared photodissociation spectroscopy and density functional theory calculations. Hydrogen bonding between H2O molecules is detected in Cu+(H2O)3 and Cu+(H2O)4 through a characteristic change in the position and intensity of OH-stretching transitions. The third and fourth waters prefer hydrogen-bonding sites in the second solvation shell rather than direct coordination to Cu+. The infrared spectroscopy verifies that the gas-phase coordination number of Cu+ in Cu+(H2O)n is two and the resulting linearly coordinated structure acts as the core of further solvation processes.
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| 内容記述 |
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2006.06.036
This work was supported in part by “Nanotechnology Support Project” and Grant-in-Aid for Scientific Research (No. 17550014) of the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan.
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| NDC分類 |
化学 [ 430 ]
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Elsevier B.V.
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| 発行日 | 2006-08-18 |
| 権利情報 |
(c) 2006 Elsevier B.V. All rights reserved.
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| 出版タイプ | Author’s Original（十分な品質であるとして、著者から正式な査読に提出される版） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2006.06.036
[DOI] http://doi.org/10.1016/j.cplett.2006.06.036
～の異版である
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