Synthesis and Structural Characterization of Multi-Molybdenum-Substituted Preyssler-type Phosphotungstates
European Journal of Inorganic Chemistry 36 巻
e202200533- 頁
2022-12-19 発行
アクセス数 : 22 件
ダウンロード数 : 11 件
今月のアクセス数 : 22 件
今月のダウンロード数 : 11 件
この文献の参照には次のURLをご利用ください : https://ir.lib.hiroshima-u.ac.jp/00056196
| ファイル情報(添付) | |
| タイトル ( eng ) |
Synthesis and Structural Characterization of Multi-Molybdenum-Substituted Preyssler-type Phosphotungstates
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| 作成者 |
Wihadi Muh. Nur Khoiru
Haioka Terufumi
Kojima Tatsuhiro
López Xavier
Ueda Tadaharu
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| 収録物名 |
European Journal of Inorganic Chemistry
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| 巻 | 36 |
| 開始ページ | e202200533 |
| 抄録 |
We report the synthesis of multi-Mo-substituted Preyssler-type phosphotungstates, [P5W30-xMoxO110Na(H2O)]14−, with different amounts of incorporated Mo via the hydrothermal reactions of H3PO4, Na2WO4, and Na2MoO4; and characterization by 31P nuclear magnetic resonance (NMR), Fourier-transform infrared (FT-IR), elemental analysis, electrospray ionization-mass spectrometry (ESI-MS), and cyclic voltammetry. The number of substituted Mo increases by increasing the amount of Na2MoO4 in the reaction mixture, and in the [P5W30-xMoxO110Na(H2O)]14−, up to penta-Mo-substituted species can be produced as mixtures of isomers with different Mo numbers and Mo positions. Single crystal X-ray structure analysis and density functional theory calculation indicate that the most suitable substitution position is the belt position.
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| 著者キーワード |
Molybdate
Polyoxometalates
Preyssler-type phosphotungstate
Self-assembly
Substitution
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| 内容記述 |
This research was supported by JSPS KAKENHI Grant Number JP21H02028 and JP18H02058 (Grant-in-aid for scientific research (B)), Grant-in-Aid for Transformative Research Area (A) “Supra-ceramics” (JSPS KAKENHI Grant Number JP22H05144), International Network on Polyoxometalate Science at Hiroshima University, JSPS Core-to-Core program, and Takahashi Industrial and Economic Research Foundation (12-003-147). M. N. K. W. gratefully acknowledges the financial support from the Indonesia Endowment Fund for Education (LPDP), Ministry of Finance, Republic of Indonesia for Ph.D. scholarship (PRJ-36/LPDP.3/2017). X. L. is grateful for the financial support of the Spanish Government (grant nr. PID2020-112762GB-I00).
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Wiley
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| 発行日 | 2022-12-19 |
| 権利情報 |
This is the peer reviewed version of the following article: M. N. Khoiru Wihadi, T. Haioka, T. Kojima, X. López, T. Ueda, T. Sano, M. Sadakane, Eur. J. Inorg. Chem. 2022, e202200533., which has been published in final form at https://doi.org/10.1002/ejic.202200533. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
This is not the published version. Please cite only the published version.
この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。
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| 出版タイプ | Accepted Manuscript（出版雑誌の一論文として受付されたもの。内容とレイアウトは出版社の投稿様式に沿ったもの） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[DOI] https://doi.org/10.1002/ejic.202200533
～の異版である
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| 助成機関名 |
日本学術振興会
Japan Society for the Promotion of Science
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| 助成機関識別子 |
[Crossref Funder] https://doi.org/10.13039/501100001691
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| 研究課題名 |
機能性材料を指向したPreyssler型タングステート自在合成法開発
Development of synthesis method of Preyssler-type phosphotungstates and application as functional materials
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| 研究課題番号 |
21H02028
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| 助成機関名 |
日本学術振興会
Japan Society for the Promotion of Science
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| 助成機関識別子 |
[Crossref Funder] https://doi.org/10.13039/501100001691
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| 研究課題名 |
機能性材料としての応用を指向した新規Preyssler型タングステートの合成
Preparation of new Preyssler-type tungstates and application as functional materials
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| 研究課題番号 |
18H02058
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| 助成機関名 |
日本学術振興会
Japan Society for the Promotion of Science
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| 助成機関識別子 |
[Crossref Funder] https://doi.org/10.13039/501100001691
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| 研究課題名 |
超セラミックスの次元・形態制御
Controls of Structural dimensionality and Crystal morphology of Supra-ceramics
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| 研究課題番号 |
22H05144
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