Interconnection of organic–inorganic hybrid nano-building blocks towards thermally robust mesoporous structures

Nanoscale Volume 13 Page 11446-11454 published_at 2021-06-23
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Title ( eng )
Interconnection of organic–inorganic hybrid nano-building blocks towards thermally robust mesoporous structures
Sato Riona
Yamazaki Wataru
Ishigaki Takamasa
Source Title
Volume 13
Start Page 11446
End Page 11454
The use of organic–inorganic hybrid nanoparticles will enable a control of the characteristics of both the nanoparticles and constructed fine structures. In this study, we report the synthesis of acrylate-intercalated layered manganese, cobalt, and nickel hydroxide nanoparticles and their assembly into ordered mesoporous structures. Polymerization of the intercalated acrylates takes place by means of a radical initiator. The formed organic network improved the thermal stability of the layered hydroxides, which results in thermally robust mesoporous structures. Additionally, it is found that the polymerization can be initiated and progressed at 200 °C without any initiators for the layered nickel hydroxide system. This allows for the scalable solid-state thermal polymerization of intercalated acrylates and the formation of thermally robust hierarchically ordered meso/macroporous powders as well as mesoporous films. The electrochemical characterization reveals that the thermally robust mesoporous films having regulated mesopores allow for the effective diffusion of molecules/solvent compared with the films having collapsed mesoporous structures.
The present work is partially supported by JSPS KAKENHI Grant Number JP20K15368, JSPS Core-to-Core Program, MEXT Leading Initiative for Excellent Young Researchers, the Foundation for the Promotion of Ion Engineering, International Network on Polyoxometalate Science at Hiroshima University, and the Izumi Science and Technology Foundation (2019-J-112).
Resource Type journal article
The Royal Society of Chemistry
Date of Issued 2021-06-23
This journal is © The Royal Society of Chemistry 2021
Open Access Article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 2040-3372
[DOI] 10.1039/d0nr08689d