Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
Chemical Communications Volume 51
Page 6297-6300
published_at 2015-02-03
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| File | |
| Title ( eng ) |
Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
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| Creator |
Takemoto Y.
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| Source Title |
Chemical Communications
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| Volume | 51 |
| Start Page | 6297 |
| End Page | 6300 |
| Abstract |
A variety of terminal alkynes are facilely convertible into cis-boryl(stannyl)alkenes with inverse regioselectivity to those of the previous borylstannylation by the copper-catalyzed three-component reaction using a masked diboron. The synthetic utility of the resulting boryl(stannyl)alkenes has been demonstrated by chemoselective coupling reactions.
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Royal Society of Chemistry
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| Date of Issued | 2015-02-03 |
| Rights |
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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| Publish Type | Version of Record |
| Access Rights | open access |
| Source Identifier |
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c5cc00439j
[DOI] https://doi.org/10.1039/c5cc00439j
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