Copper-Catalyzed Arylstannylation of Arynes in Sequence
Chemical Communications Volume 55 Issue 46
Page 6503-6506
published_at 2019-06-11
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2020-06-11
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Title ( eng ) |
Copper-Catalyzed Arylstannylation of Arynes in Sequence
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Creator |
Tanaka Hideya
Kuriki Hitoshi
Kubo Teruhiko
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Source Title |
Chemical Communications
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Volume | 55 |
Issue | 46 |
Start Page | 6503 |
End Page | 6506 |
Abstract |
Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.
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Descriptions |
This work was financially supported by JSPS KAKENHI Grant Number JP17K05864.
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Language |
eng
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Resource Type | journal article |
Publisher |
Royal Society of Chemistry
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Date of Issued | 2019-06-11 |
Rights |
© The Royal Society of Chemistry 2019
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
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Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
Electronic supplementary information (ESI) available: Experimental procedures and characterization data. See DOI: 10.1039/c9cc02738f
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c9cc02738f
[PMID] 31099347
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Remark | Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months. |