Copper-Catalyzed Arylstannylation of Arynes in Sequence

Chemical Communications Volume 55 Issue 46 Page 6503-6506 published_at 2019-06-11
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Title ( eng )
Copper-Catalyzed Arylstannylation of Arynes in Sequence
Tanaka Hideya
Kuriki Hitoshi
Kubo Teruhiko
Source Title
Chemical Communications
Volume 55
Issue 46
Start Page 6503
End Page 6506
Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.
This work was financially supported by JSPS KAKENHI Grant Number JP17K05864.
Resource Type journal article
Royal Society of Chemistry
Date of Issued 2019-06-11
© The Royal Society of Chemistry 2019
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
Publish Type Author’s Original
Access Rights open access
Source Identifier
Electronic supplementary information (ESI) available: Experimental procedures and characterization data. See DOI: 10.1039/c9cc02738f
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c9cc02738f
[PMID] 31099347
Remark Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months.