Vibrational and electronic spectra of (benzene-benzyl alcohol)+. Predominance of charge resonance interaction over hydrogen bonding interaction
Chemical Physics Letters 321 巻 5–6 号
406-410 頁
2000-05-05 発行
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| ファイル情報(添付) | |
| タイトル ( eng ) |
Vibrational and electronic spectra of (benzene-benzyl alcohol)+. Predominance of charge resonance interaction over hydrogen bonding interaction
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| 作成者 |
Ohashi Kazuhiko
Izutsu Hironobu
Hino Kazuyuki
Nishi Nobuyuki
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| 収録物名 |
Chemical Physics Letters
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| 巻 | 321 |
| 号 | 5–6 |
| 開始ページ | 406 |
| 終了ページ | 410 |
| 抄録 |
Vibrational and electronic spectra of the benzene–benzyl alcohol hetero-dimer ion are measured by photodissociation spectroscopy. The vibrational spectrum shows a prominent band at 3662±3 cm-1, which is assigned to the stretching vibration of the OH group free from intermolecular perturbations. The electronic spectrum shows a broad band around 950 nm, which arises from a charge resonance interaction between the aromatic rings. These results suggest that the ion has a sandwich-like structure suitable for the resonance interaction, without the hydrogen bond between the OH group of benzyl alcohol and the π-electrons of benzene.
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| 内容記述 |
This work was supported in part by the Joint Studies Program (1999) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (Nos. 09740450 and 11440177) from the Ministry of Education, Science, Sports and Culture of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2000, available online: http://doi.org/10.1016/S0009-2614(00)00379-1
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| NDC分類 |
化学 [ 430 ]
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Elsevier B.V.
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| 発行日 | 2000-05-05 |
| 権利情報 |
(c) 2000 Elsevier Science B.V. All rights reserved.
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| 出版タイプ | Author’s Original（十分な品質であるとして、著者から正式な査読に提出される版） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[ISSN] 0009-2614
[DOI] 10.1016/S0009-2614(00)00379-1
[DOI] http://doi.org/10.1016/S0009-2614(00)00379-1
～の異版である
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