A crotofolane-type diterpenoid and a rearranged nor-crotofolane-type diterpenoid with a new skeleton from the stems of Croton cascarilloides
Tetrahedron Letters Volume 51 Issue 33
Page 4320-4322
published_at 2010-08-18
アクセス数 : 630 件
ダウンロード数 : 218 件
今月のアクセス数 : 3 件
今月のダウンロード数 : 3 件
この文献の参照には次のURLをご利用ください : https://ir.lib.hiroshima-u.ac.jp/00030416
| File | |
| Title ( eng ) |
A crotofolane-type diterpenoid and a rearranged nor-crotofolane-type diterpenoid with a new skeleton from the stems of Croton cascarilloides
|
| Creator |
Kawakami Susumu
Shinzato Takakazu
Takeda Yoshio
Kawahata Masatoshi
Yamaguchi Kentaro
|
| Source Title |
Tetrahedron Letters
|
| Volume | 51 |
| Issue | 33 |
| Start Page | 4320 |
| End Page | 4322 |
| Abstract |
From the stems of Croton cascarilloides collected in the Okinawa Islands, a structurally rare crotofolane-type diterpenoid (1) and a rearranged nor-crotofalane, a new skeletal diterpenoid (2), were isolated. The structures were determined by X-ray crystallographic analyses, establishing their absolute stereostructures for the first time. Compound 2 was probably biosynthesized from 1 through several steps, such as decarboxylation, oxidation, C-C bond migration, etc.
|
| Keywords |
Croton cascarilloides
Euphorbiaccae
Crotofolane
Diterpenoid
|
| NDC |
Medical sciences [ 490 ]
|
| Language |
eng
|
| Resource Type | journal article |
| Publisher |
Pergamon-Elsevier Science LTD
|
| Date of Issued | 2010-08-18 |
| Rights |
Copyright (c) 2010 Elsevier Ltd
|
| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0040-4039
[DOI] 10.1016/j.tetlet.2010.06.033
[NCID] AA00861801
[DOI] http://dx.doi.org/10.1016/j.tetlet.2010.06.033
|
