Synthesis of calcium phosphate hydrogel from waste incineration fly ash and its application to fuel cell

Journal of Environmental Management 90 巻 8 号 2709-2714 頁 2009 発行
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タイトル ( eng )
Synthesis of calcium phosphate hydrogel from waste incineration fly ash and its application to fuel cell
作成者
Kidoguchi Satoshi
Arimitsu Naoki
Jikihara Kenji
収録物名
Journal of Environmental Management
90
8
開始ページ 2709
終了ページ 2714
抄録
Waste incineration fly ash was successfully recycled to calcium phosphate hydrogel, a type of fast proton conductor. The crystallized hydrogel from incineration fly ash had a lower electric conductivity and a lower crystallinity than that from calcium carbonate reagent. However, the difference in electric conductivity between these crystallized hydrogels decreases with temperature. This was due to the presence of potassium in the incineration fly ash. The fuel cell with a membrane electrode assembly (MEA) using the calcium phosphate hydrogel membrane prepared from incineration fly ash was observed to generate electricity. The performance of this fuel cell was almost equal to that of a mixture of K2CO3 and CaCO3 reagents; further, the performance of the former was superior to the fuel cell with a perfluorosulfonic polymer membrane at temperatures greater than approximately 85 degrees C.
著者キーワード
Waste incineration fly ash
Calcium phosphate hydrogel
Fast proton conductor
Electrolyte
Fuel cell
NDC分類
化学工業 [ 570 ]
言語
英語
資源タイプ 学術雑誌論文
出版者
Academic Press Ltd
Elsevier Science Ltd
発行日 2009
権利情報
Copyright (c) 2009 Elsevier Ltd
出版タイプ Author’s Original(十分な品質であるとして、著者から正式な査読に提出される版)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 0301-4797
[DOI] 10.1016/j.jenvman.2009.02.014
[NCID] AA00251899
[DOI] http://dx.doi.org/10.1016/j.jenvman.2009.02.014