Synthesis and decomposition reactions of metal amides in metal-N-H hydrogen storage system
Journal of Power Sources Volume 156 Issue 2
Page 166-170
published_at 2006-06-01
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| File | |
| Title ( eng ) |
Synthesis and decomposition reactions of metal amides in metal-N-H hydrogen storage system
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| Creator |
Leng Haiyan
Hino Satoshi
Hanada Nobuko
Isobe Shigehito
Fujii Hironobu
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| Source Title |
Journal of Power Sources
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| Volume | 156 |
| Issue | 2 |
| Start Page | 166 |
| End Page | 170 |
| Abstract |
After some metal amides M(NH2)x such as LiNH2, NaNH2, Mg(NH2)2 and Ca(NH2)2 were synthesized by ball milling the corresponding metal hydrides MHx under ammonia atmosphere at room temperature, their thermal decomposition properties were examined, which play important roles for designing a new family of novel Metal-N-H systems. The results indicate that the kinetics of their synthesizing reactions are faster in the order of Na amide > Li amide > Ca amide > Mg amide, while both Mg(NH2)2 and Ca(NH2)2 decompose and emit NH3 at lower temperature than LiNH2.
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| Keywords |
Hydrogen storage
Metal hydride
Ammonia
Metal amide
Reactive ball milling
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| NDC |
Physics [ 420 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B.V.
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| Date of Issued | 2006-06-01 |
| Rights |
Copyright (c) 2005 Elsevier B.V.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0378-7753
[DOI] 10.1016/j.jpowsour.2005.03.228
[NCID] AA00705373
[DOI] http://dx.doi.org/10.1016/j.jpowsour.2005.03.228
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