Dehydriding reaction of metal hydrides and alkali borohydrides enhanced by microwave irradiation

Applied Physics Letters 88 巻 11 号 112104-1-112104-3 頁 2006-03-14 発行
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タイトル ( eng )
Dehydriding reaction of metal hydrides and alkali borohydrides enhanced by microwave irradiation
作成者
Nakamori Yuko
Orimo Shin-ichi
収録物名
Applied Physics Letters
88
11
開始ページ 112104-1
終了ページ 112104-3
抄録
Effects of microwave irradiation on metal hydrides (LiH, NaH, MgH 2, CaH2, and TiH2) and alkali borohydrides (LiBH4, NaBH4, and KBH4) were systematically investigated for the first time. TiH2 was heated to 600 K by microwave irradiation for 3.5 min, at which less than 0.16 mass % of hydrogen was desorbed from surface of the powder. On the other hand, LiBH4 was heated rapidly above 380 K, at which almost all hydrogen, 13 mass %, was desorbed. The rapid heating of TiH2 is mainly due to conductive loss, while that of LiBH4 is related to a structural transition at approximately 380 K.
言語
英語
資源タイプ 学術雑誌論文
出版者
American Institute of Physics
発行日 2006-03-14
権利情報
Copyright (c) 2006 American Institute of Physics.
出版タイプ Version of Record(出版社版。早期公開を含む)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 0003-6951
[DOI] 10.1063/1.2185079
[NCID] AA00543431
[DOI] http://dx.doi.org/10.1063/1.2185079