Core-level x-ray photoemission on NiO in the impurity limit

Physical Review B - Condensed Matter and Materials Physics 61 巻 20 号 13 403-13 409 頁 2000-05-15 発行
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タイトル ( eng )
Core-level x-ray photoemission on NiO in the impurity limit
作成者
Altieri S.
Tjeng L. H.
Sawatzky G. A.
収録物名
Physical Review B - Condensed Matter and Materials Physics
61
20
開始ページ 13 403
終了ページ 13 409
抄録
We present a core level X-ray photoelectron spectroscopy study of NixMg12xO crystals with 0.03<x<1. We show that nonlocal effects involving inter-Ni-site fluctuations strongly influence the Ni 2p core-level spectra for higher Ni concentrations including NiO itself. It is only in the very dilute Ni limit that the core-level spectra can be described in terms of an Anderson impurity model which also must include a realistic band structure for the O 2p. Moreover, it is only in this limit that a single-site model can explain the core-level and valence-band spectra as well as the optical data by using one consistent set of parameter values. These results consolidate the concepts of nonlocal screening and provide a better understanding of the electronic structure of NiO.
言語
英語
資源タイプ 学術雑誌論文
出版者
American Physical Society
発行日 2000-05-15
権利情報
Copyright (c) 2000 American Physical Society.
出版タイプ Version of Record(出版社版。早期公開を含む)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 1098-0121
[DOI] 10.1103/PhysRevB.61.13403
[NCID] AA11187113
[DOI] http://dx.doi.org/10.1103/PhysRevB.61.13403