Asymmetric reductive cyclization using the intramolecular conjugate addition of enolates onto α,β-unsaturated sulfoxides

Tetrahedron letters Volume 39 Issue 1-2 Page 47-50 published_at 1998-01-01
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Title ( eng )
Asymmetric reductive cyclization using the intramolecular conjugate addition of enolates onto α,β-unsaturated sulfoxides
Creator
Yoshizaki Hiroki
Tanaka Tadashi
Yoshii Eiichi
Koizumi Toru
Source Title
Tetrahedron letters
Volume 39
Issue 1-2
Start Page 47
End Page 50
Abstract
Li(sec-Bu)3BH-mediated reductive cyclization of optically pure 8-((S)-p-tolylsulfinyl)-(2E,7Z)-octadienoate 9 and 7-(p-tolylsulfinyl)-2,6-heptadienoate 16 afforded trans-2-((p-tolylsulfinyl)-methyl)cyclohexane-1-carboxylate and trans-2-((p-tolylsulfinyl)methyl)cyclopentane-1-carboxylate, respectively, as a single isomer.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Elsevier B.V.
Date of Issued 1998-01-01
Rights
Copyright (c) 1998 Elsevier B.V.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0040-4039
[DOI] 10.1016/S0040-4039(97)10414-2
[DOI] http://dx.doi.org/10.1016/S0040-4039(97)10414-2 isVersionOf