Infrared photodissociation spectroscopy of aniline+-(water)1,2 and aniline+-(methanol)1,2
Chemical Physics Letters Volume 358 Issue 5–6
Page 419-425
published_at 2002-06-07
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Title ( eng ) |
Infrared photodissociation spectroscopy of aniline+-(water)1,2 and aniline+-(methanol)1,2
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Creator |
Honkawa Yoshiki
Ohashi Kazuhiko
Nishi Nobuyuki
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Source Title |
Chemical Physics Letters
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Volume | 358 |
Issue | 5–6 |
Start Page | 419 |
End Page | 425 |
Abstract |
Infrared photodissociation spectra of the aniline ion solvated by water and methanol molecules are measured in the 2600–3800 cm-1 region. Substantially red-shifted and broadened transitions are distinctly observed at 3105 and 2915 cm-1 for aniline+-(H2O)1 and aniline+-(CH3OH)1, respectively, and assigned to the stretching vibration of the hydrogen-bonded NH oscillator of the aniline+ moiety. The spectra of aniline+-(H2O)2 and aniline+-(CH3OH)2 demonstrate a large perturbation to both of the NH oscillators, indicating that each NH bond is bound to a solvent molecule in the most stable structure.
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Descriptions |
This work was supported in part by the Joint Studies Program (2001) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 11440177) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2002, available online: http://doi.org/10.1016/S0009-2614(02)00641-3
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NDC |
Chemistry [ 430 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
Elsevier B.V.
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Date of Issued | 2002-06-07 |
Rights |
(c) 2002 Elsevier Science B.V. All rights reserved.
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Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
[ISSN] 0009-2614
[DOI] 10.1016/S0009-2614(02)00641-3
[DOI] http://doi.org/10.1016/S0009-2614(02)00641-3
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