Ionic fragmentation processes of core-excited α-alanine in gas phase

Chemical Physics Letters Volume 417 Issue 1-3 Page 246-250 published_at 2006-09
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Title ( eng )
Ionic fragmentation processes of core-excited α-alanine in gas phase
Creator
Morita Masaki
Mori Mitsuo
Sunami Tetsuzi
Source Title
Chemical Physics Letters
Volume 417
Issue 1-3
Start Page 246
End Page 250
Abstract
Ionic fragmentation of core-excited α-alanine in gas phase was observed. The most dominant ionic species is COOH+ for all core-ionizations at C 1s, N 1s, and O 1s. An increase in COO+ and a decrease in COOH+, which were observed as core-hole atom selectivity for the O 1s ionization, are explained by the enhancement of O-H bond scission. Further state-selective O-H bond scission, observed at the O 1s second peak, is attributed to the OOH 1s → 3s/σ* transition.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Elsevier
Date of Issued 2006-09
Rights
Copyright (c) 2006 Elsevier Ltd.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2005.09.039
[NCID] AA00602122
[DOI] http://dx.doi.org/10.1016/j.cplett.2005.09.039 isVersionOf