Tandem Epoxysilane Rearrangement/Wittig-Type Reactions Using γ-Phosphinoyl- and γ-Phosphonio-α,β-epoxysilane
Tetrahedron Letters Volume 47 Issue 52
Page 9271-9273
published_at 2006-12-25
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| File | |
| Title ( eng ) |
Tandem Epoxysilane Rearrangement/Wittig-Type Reactions Using γ-Phosphinoyl- and γ-Phosphonio-α,β-epoxysilane
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| Creator |
Horai Mai
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| Source Title |
Tetrahedron Letters
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| Volume | 47 |
| Issue | 52 |
| Start Page | 9271 |
| End Page | 9273 |
| Abstract |
Reaction of γ-phosphinoyl- and γ-phosphonio-α,β-epoxysilane with a base followed by addition of a ketone or an aldehyde afforded dienol silyl ether derivatives via a tandem process that involves base-induced ring opening of the epoxide, Brook rearrangement, and Wittig-type reaction.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier
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| Date of Issued | 2006-12-25 |
| Rights |
Copyright (c) 2006 Elsevier Ltd.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0040-4039
[DOI] 10.1016/j.tetlet.2006.10.121
[NCID] AA00861801
[DOI] http://dx.doi.org/10.1016/j.tetlet.2006.10.121
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