Formation of H3O+ by the soft X-ray ionization of ethanol clusters
Chemical Physics Letters Volume 433 Issue 1-3
Page 43-47
published_at 2006-12-29
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| File | |
| Title ( eng ) |
Formation of H3O+ by the soft X-ray ionization of ethanol clusters
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| Creator |
Tamenori Yusuke
Tabayashi Kiyohiko
Gejo Tatsuo
Honma Kenji
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| Source Title |
Chemical Physics Letters
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| Volume | 433 |
| Issue | 1-3 |
| Start Page | 43 |
| End Page | 47 |
| Abstract |
Time-of-flight mass spectra have been measured for inner-shell ionization of ethanol molecules, its clusters, and methanol clusters at the oxygen K-edge regions. Only in the case of the ethanol clusters, a fairly intense signal corresponding to H3O+ has been observed. The measurements for ethanol-d1 (C2H5OD) suggest that at least one H atom in the H3O+ ion originates from the C2H5 group of neighbouring ethanol. It is proposed that in addition to the O-H--OH type hydrogen bonding in the ethanol clusters, the H in the C2H5 group and OH interact with each other.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier
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| Date of Issued | 2006-12-29 |
| Rights |
Copyright (c) 2006 Elsevier Ltd.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2006.11.038
[NCID] AA00602122
[DOI] http://dx.doi.org/10.1016/j.cplett.2006.11.038
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