Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
Chemical Communications Volume 51
Page 10616-10619
published_at 2015-04-27
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| File | |
| Title ( eng ) |
Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
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| Creator |
Shinke A.
Kawano Y.
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| Source Title |
Chemical Communications
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| Volume | 51 |
| Start Page | 10616 |
| End Page | 10619 |
| Abstract |
A variety of branched alkenylstannanes can directly be synthesized with excellent α-selectivity by the copper-catalyzed hydrostannylation using a distannane or a silylstannane, irrespective of the electronic and steric characteristics of terminal alkynes employed. Synthetic utility of the resulting branched alkenylstannane has been demonstrated by the total synthesis of bexarotene.
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Royal Society of Chemistry
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| Date of Issued | 2015-04-27 |
| Rights |
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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| Publish Type | Version of Record |
| Access Rights | open access |
| Source Identifier |
[ISSN] 1359-7345
[ISSN] 1364-548X
[DOI] 10.1039/c5cc02720a
[DOI] https://doi.org/10.1039/c5cc02720a
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