Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

Organic Chemistry Frontiers Volume 4 Issue 7 Page 1215-1219 published_at 2017-04-10
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Title ( eng )
Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)
Creator
Takemoto Yuki
Kamio Shintaro
Source Title
Organic Chemistry Frontiers
Volume 4
Issue 7
Start Page 1215
End Page 1219
Abstract
Substitutional borylation of C(sp3 or sp2)–halogen bonds with an unsymmetrical diboron [(pin)B–B(dan)] was found to proceed smoothly under copper catalysis. A variety of masked alkyl-, alkenyl- and arylboron compounds [R–B(dan)] were straightforwardly accessible with high functional group compatibility in high yield.
Descriptions
This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding.
Language
eng
Resource Type journal article
Publisher
Royal Society of Chemistry
Date of Issued 2017-04-10
Rights
This journal is © the Partner Organisations 2017
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 2052-4129
[DOI] 10.1039/C7QO00084G
[DOI] https://doi.org/10.1039/C7QO00084G