Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
Organometallics Volume 36 Issue 7
Page 1345-1351
published_at 2017-03-24
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| File | |
| Title ( eng ) |
Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
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| Creator |
Kimura Miki
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| Source Title |
Organometallics
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| Volume | 36 |
| Issue | 7 |
| Start Page | 1345 |
| End Page | 1351 |
| Abstract |
Tin fluorides were found to be suitable electrophiles for the copper-catalyzed borylstannylation of terminal alkynes with bis(pinacolato)diboron to afford cis-vic-boryl(stannyl)alkenes straightforwardly. A fluorine atom proved to play a pivotal role in generating a key catalytic intermediate, a borylcopper species, both in the induction period and in the s-bond metathesis step.
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| Descriptions |
This work was financially supported by JSPS KAKENHI Grant Number JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding.
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
American Chemical Society
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| Date of Issued | 2017-03-24 |
| Rights |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.7b00058.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0276-7333
[ISSN] 1520-6041
[DOI] 10.1021/acs.organomet.7b00058
[DOI] https://doi.org/10.1021/acs.organomet.7b00058
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