Lipid-membrane-incorporated hydrophobic photochromic molecules prepared by the exchange method using cyclodextrins
Organic and Biomolecular Chemistry Volume 13 Issue 22
Page 6175-6182
published_at 2015-03-11
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OBC_13-22_6175.pdf
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fulltext
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Title ( eng ) |
Lipid-membrane-incorporated hydrophobic photochromic molecules prepared by the exchange method using cyclodextrins
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Creator |
Hino Shodai
Ashizawa Kengo
Kikuchi Jun-ichi
Tsukamoto Manami
Yasuhara Kazuma
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Source Title |
Organic and Biomolecular Chemistry
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Volume | 13 |
Issue | 22 |
Start Page | 6175 |
End Page | 6182 |
Abstract |
It was found that the exchange method for the preparation of lipid-membrane-incorporated guest molecules was applicable not only to fullerenes but also to other hydrophobic molecules such as azobenzene and stilbene. Advantages of this method are that the long-term stability of lipid-membrane-incorporated azobenzene solution and the maximum ratio of [stilbene]/[lipid] were higher than those prepared by the classical method, which we call the ‘premixing method’. Photoisomerisations of these photochromic guest molecules in the lipid membranes maintained the morphology of liposomes.
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Descriptions |
This file includes Electronic Supplementary Information.
This work was supported by JSPS KAKENHI a Grant-in-Aid for Scientific Research (B) (Grant No. 25288037), a Grant-in-Aid for Challenging Exploratory Research (Grant Nos. 24655128 and 25650053) and a Grant-in-Aid for Young Scientists (A) (Grant No. 24681028).
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NDC |
Chemistry [ 430 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
Royal Society of Chemistry
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Date of Issued | 2015-03-11 |
Rights |
Copyright (c) 2015 The Royal Society of Chemistry
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
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Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
[ISSN] 1477-0520
[DOI] 10.1039/c5ob00240k
[PMID] 25790016
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