Lipid-membrane-incorporated hydrophobic photochromic molecules prepared by the exchange method using cyclodextrins

Organic and Biomolecular Chemistry Volume 13 Issue 22 Page 6175-6182 published_at 2015-03-11
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Title ( eng )
Lipid-membrane-incorporated hydrophobic photochromic molecules prepared by the exchange method using cyclodextrins
Creator
Hino Shodai
Ashizawa Kengo
Kikuchi Jun-ichi
Tsukamoto Manami
Yasuhara Kazuma
Source Title
Organic and Biomolecular Chemistry
Volume 13
Issue 22
Start Page 6175
End Page 6182
Abstract
It was found that the exchange method for the preparation of lipid-membrane-incorporated guest molecules was applicable not only to fullerenes but also to other hydrophobic molecules such as azobenzene and stilbene. Advantages of this method are that the long-term stability of lipid-membrane-incorporated azobenzene solution and the maximum ratio of [stilbene]/[lipid] were higher than those prepared by the classical method, which we call the ‘premixing method’. Photoisomerisations of these photochromic guest molecules in the lipid membranes maintained the morphology of liposomes.
Descriptions
This file includes Electronic Supplementary Information.
This work was supported by JSPS KAKENHI a Grant-in-Aid for Scientific Research (B) (Grant No. 25288037), a Grant-in-Aid for Challenging Exploratory Research (Grant Nos. 24655128 and 25650053) and a Grant-in-Aid for Young Scientists (A) (Grant No. 24681028).
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Royal Society of Chemistry
Date of Issued 2015-03-11
Rights
Copyright (c) 2015 The Royal Society of Chemistry
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 1477-0520
[DOI] 10.1039/c5ob00240k
[PMID] 25790016