Infrared photodissociation spectroscopy of benzene trimer ions. Switching of the dimer ion core in vibrationally excited states
Chemical Physics Letters Volume 279 Issue 1–2
Page 73-78
published_at 1997-11-07
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| File | |
| Title ( eng ) |
Infrared photodissociation spectroscopy of benzene trimer ions. Switching of the dimer ion core in vibrationally excited states
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| Creator |
Ohashi Kazuhiko
Nishi Nobuyuki
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| Source Title |
Chemical Physics Letters
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| Volume | 279 |
| Issue | 1–2 |
| Start Page | 73 |
| End Page | 78 |
| Abstract |
A vibrational spectrum of benzene trimer ion, (C6H6)3+, was measured in the 2900–3100 cm-1 region by infrared photodissociation spectroscopy. An intense band at 2986 cm-1 was attributed to a C–H stretching vibration of the dimer ion core in (C6H6)3+. The spectra of isotopically mixed benzene trimer ions with benzene-d6 molecules were also obtained. From the analysis of asymmetric band shape, a switching of the dimer ion core is proposed to occur in the vibrationally excited state prior to the vibrational predissociation.
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| Descriptions |
Y.I. received financial support from JSPS Research Fellowships for Young Scientists.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 1997, available online: http://doi.org/10.1016/S0009-2614(97)00964-0
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B.V.
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| Date of Issued | 1997-11-07 |
| Rights |
(c) 1997 Elsevier Science B.V. All rights reserved.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] http://doi.org/10.1016/S0009-2614(97)00964-0
isVersionOf
[DOI] 10.1016/S0009-2614(97)00964-0
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