Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters : Encapsulation of a neutral atom in a molecular bowl

The Journal of Chemical Physics Volume 126 Page 141101-1-141101-4 published_at 2007-04-10
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Title ( eng )
Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters : Encapsulation of a neutral atom in a molecular bowl
Creator
Hodono Yuki
Ito Takafumi
Source Title
The Journal of Chemical Physics
The Journal of Chemical Physics
Volume 126
Start Page 141101-1
End Page 141101-4
Abstract
The encapsulation of neutral guest has been studied for calix[4]arene (C4A) by forming van der Waals clusters with Ar and Ne in supersonic jets. The electronic transitions of these clusters suggest that the first Ar (Ne) is encapsulated inside the C4A cavity, while the next atoms are bound outside.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
American Institute of Physics
Date of Issued 2007-04-10
Rights
Copyright (c) 2007 American Institute of Physics
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 0021-9606
[DOI] 10.1063/1.2723068
[DOI] http://dx.doi.org/10.1063/1.2723068 isVersionOf