Electronic and vibrational spectra of aniline―benzene heterodimer and aniline homo-dimer ions
Chemical Physics Letters Volume 323 Issue 1-2
Page 43-48
published_at 2000-06
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| File | |
| Title ( eng ) |
Electronic and vibrational spectra of aniline―benzene heterodimer and aniline homo-dimer ions
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| Creator |
Ohashi Kazuhiko
Izutsu Hironobu
Hino Kazuyuki
Yamamoto Norifumi
Nishi Nobuyuki
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| Source Title |
Chemical Physics Letters
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| Volume | 323 |
| Issue | 1-2 |
| Start Page | 43 |
| End Page | 48 |
| Abstract |
Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B.V.
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| Date of Issued | 2000-06 |
| Rights |
Copyright (c) 2000 Elsevier Science B.V.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] 10.1016/S0009-2614(00)00497-8
[DOI] http://dx.doi.org/10.1016/S0009-2614(00)00497-8
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