Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands

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Title ( eng )
Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands
Title ( jpn )
マーチンリガンドを有する5配位有機リン化合物の立体化学と反応
Creator
Kajiyama Kazumasa
Descriptions
Contents
Chapter 1.General Introduction
 A.General Introduction / p1
 B.References / p12
Chapter 2.Syntheses and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H(Apical) Phosphoranes Bearing a Hydroxy Group.
 A.Introduction / p16
 B.Results and Discussion / p18
 C.Experimental Section / p38
 D.References / p55
Chapter 3.First Characterization of 10-P-5 Spirophosphoranes with an Apical Carbon-Equatorial Oxygen ring. Kinetic Studies on Pseudorotation.
 A.Introduction / p57
 B.Results and Discussion / p60
 C.Experimental Section / p75
 D.References / p99
Chapter 4.Kinetic Studies of Thermal Cyclization Reactions of P-H(apical) Phosphoranes Bearing a Hydroxy Group.
 A.Introduction / p101
 B.Results and Discussion / p104
 C.Experimental Section / p115
 D.References / p136
Acknowledgements / p138
List of Publications / p139
NDC
Chemistry [ 430 ]
Language
eng
Resource Type doctoral thesis
Rights
Copyright(c) by Author
Publish Type Not Applicable (or Unknown)
Access Rights open access
Source Identifier
*(4) Synthesis and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H (apical) Phosphoranes Bearing a Hydroxyl Group and Their Thermal Cyclization. Kajiyama, K.; Kojima, S.; Akiba, K.-y. Tetrahedron Lett. 1996, 37, 8409-8412. references
*(5) First Characterization of a 10-P-5 Spirophosphorane with an Apical Carbon-Equatorial Oxygen Ring. Kinetic Studies on Pseudorotation of Stereoisomers. Kojima, S.; Kajiyama, K.; Nakamoto, M.; Akiba, K.-y. J. A in. Chem. Soc. 1996, 118, 12866-12867. references
[DOI] http://dx.doi.org/10.1016/0040-4039(96)01923-5 references
[DOI] http://dx.doi.org/10.1021/ja9621408 references
Dissertation Number 甲第1583号
Degree Name
Date of Granted 1997-03-25
Degree Grantors
広島大学