Stereochmistry of Tetra- and Pentacoordinate Organic Compounds of Phosphorus and Antimony
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| Title ( eng ) |
Stereochmistry of Tetra- and Pentacoordinate Organic Compounds of Phosphorus and Antimony
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| Title ( jpn ) |
4配位および5配位有機リンおよびアンチモン化合物の立体化学
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| Creator | |
| Descriptions |
Contents
General Introduction / p1 References / p18 Chapter1.Preparation of Optically Active Phosphine Oxides via Wittig Type Rearrangement and Phosphine Sulfides via Alkylation of Lithium Phosphinothioites. 1.Introduction / p21 2.Results and Discussion / p25 3.Experimental / p50 4.References / p70 Chapter2.Characterization of the FirstEnantiomericPairs of Stereochemically Definable Hypervalent 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus. 1.Introduction / p72 2.Results and Discussion / p74 3.Experimental / p97 4.References / p108 Chapter3.The First Stereochemical Characterization of Configurationally Stable Diastereomers of Hypervalent 10-Sb-5 Stiboranes and Acceleration of Intramolecular Permutation by Donor Solvents 1.Introduction / p110 2.Results and Discussion / p112 3.Experimental / p137 4.References / p142 List of Publications / p145 |
| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | doctoral thesis |
| Rights |
Copyright(c) by Author
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| Publish Type | Not Applicable (or Unknown) |
| Access Rights | open access |
| Source Identifier |
*(1) The Wittig Rearrangement of Chiral Phosphinothioates Induced by the Tin-Lithium Transmetallation. Kawashima, T.; Kojima, S.; Miyake, T.; Inamoto, N. Tetrahedron Lett. 1989, 201-204.
references
*(2) The Optically Active Phosphinodithioates. Synthesis and Conversion to Optically Active Phosphine Sulfides. Kawashima, T.; Kojima, S.; Inamoto, N. Chem. Lett. 1989, 849-852.
references
*(3) Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex. Akiba, K.-y.; Nakata, H.; Yamamoto, Y.; Kojima, S. Chem. Lett. 1992, 1559-1562.
references
(4) Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes. Akiba, K.-y. ; Ito, Y.; Kondo, F.; Ohashi, N.; Sakaguchi, A.; Kojima, S.; Yamamoto, Y. Chem. Lett. 1992, 1562-1566.
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(5) 121Sb Mossbauer Spectra of Hexafluorocumyl Alcohol Complexes of Sb(V) and of Sb(III) with Negative Quadrupole Coupling Constants. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y. Chem. Lett. 1993, 2037-2040.
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(6) 121Sb and 127I Mossbauer Spectroscopic Study on Sb-I Hypervalent Bonds in Trigonal Bipyramidal Antimony (V) Complexes. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y.; Ito, Y. Hyperfine Interactions 1994, 84, 439-446.
references
*(7) The Wittig Rearrangement of Chiral S-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides. Kawashima, T.; Kojima, S.; Inamoto, N Bull. Chem. Soc. Jpn. 1994, 67, 2603-2606.
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*(8) Characterization of an Optically Active Pentacoordinate Phosphorane with Asymmetry Only at Phosphorus. Kojima, S.; Kajiyama, K.; Akiba, K.-y. Tetrahedron Lett. 1994, 7037-7040.
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[DOI] http://dx.doi.org/10.1016/S0040-4039(00)95159-1
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[DOI] http://dx.doi.org/10.1246/cl.1989.849
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[DOI] http://dx.doi.org/10.1246/cl.1992.1559
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[DOI] http://dx.doi.org/10.1246/cl.1992.1563
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[DOI] http://dx.doi.org/10.1246/cl.1993.2037
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[DOI] http://dx.doi.org/10.1007/BF02060694
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[DOI] http://dx.doi.org/10.1246/bcsj.67.2603
references
[DOI] http://dx.doi.org/10.1016/0040-4039(94)88219-3
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| Dissertation Number | 乙第2677号 |
| Degree Name | |
| Date of Granted | 1995-03-07 |
| Degree Grantors |
広島大学
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