Synthesis and Chromic Behaviors of Dithienosiloles with Push-Pull Substituents Toward VOC Detection

Molecular Crystals and Liquid Crystals Volume 529 Page 1-9 published_at 2010-01
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Title ( eng )
Synthesis and Chromic Behaviors of Dithienosiloles with Push-Pull Substituents Toward VOC Detection
Creator
Tanaka Daiki
Lee Kwang-Hoi
Kurushima Yasunori
Kajiwara Shotaro
Kunai Atsutaka
Kunugi Yoshihito
Source Title
Molecular Crystals and Liquid Crystals
Volume 529
Start Page 1
End Page 9
Abstract
2-Methylthio- and 2-n-hexylthienyl-6-(tricyanoethenyl)-4,4-diphenyldithienosilole were prepared as novel push-pull type compounds. These compounds exhibit solvatochromic behaviors with respect to their UV-vis absorption and emission spectra. Clear vapor chromism is also observed for their thin solid films and the color changed clearly on exposure of the films to organic solvent vapors, indicating the potential applications to VOC sensors.
Keywords
Chromic material
push-pull compound
sensor material
silole
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Taylor & Francis Ltd
Date of Issued 2010-01
Rights
Copyright (c) 2010 Taylor & Francis. This is an electronic version of an article published in "Molecular Crystals and Liquid Crystals, Volume 529, January 2010, pages 1 - 9" Disability and Rehabilitation is available at: http://dx.doi.org/10.1080/15421406.2010.495642
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 1542-1406
[DOI] 10.1080/15421406.2010.495642
[NCID] AA11836169
[DOI] http://dx.doi.org/10.1080/15421406.2010.495642