Microtropiosides A-F : ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae)
Phytochemistry Volume 71 Issue 5-6
Page 675-681
published_at 2010-04
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Title ( eng ) |
Microtropiosides A-F : ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae)
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Creator |
Koyama Yuka
Shinzato Takakazu
Takeda Yoshio
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Source Title |
Phytochemistry
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Volume | 71 |
Issue | 5-6 |
Start Page | 675 |
End Page | 681 |
Abstract |
From a 1-BuOH-soluble fraction of a MeOH extract of the leaves of M. japonica, collected in the Okinawa islands, six new ent-labdane glucosides, named microtropiosides A-F, were isolated together with one known acyclic sesquiterpene glucoside. The structures of the new compounds were elucidated by a combination of spectroscopic analyses, and their absolute configurations by application of the β-D-glucopyranosylation-induced shift-trend rule in the 13C NMR spectroscopy and the modified Mosher's method.
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Keywords |
Microtropis japonica
Celastraceae
ent-Labdane glucoside
Microtropioside
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NDC |
Medical sciences [ 490 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
Pergamon-Elsevier Science LTD
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Date of Issued | 2010-04 |
Rights |
Copyright (c) 2010 Elsevier Ltd
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Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
[ISSN] 0031-9422
[DOI] 10.1016/j.phytochem.2010.01.004
[NCID] AA00774558
[DOI] http://dx.doi.org/10.1016/j.phytochem.2010.01.004
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