Microtropiosides A-F : ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae)

Phytochemistry Volume 71 Issue 5-6 Page 675-681 published_at 2010-04
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Title ( eng )
Microtropiosides A-F : ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae)
Creator
Koyama Yuka
Shinzato Takakazu
Takeda Yoshio
Source Title
Phytochemistry
Volume 71
Issue 5-6
Start Page 675
End Page 681
Abstract
From a 1-BuOH-soluble fraction of a MeOH extract of the leaves of M. japonica, collected in the Okinawa islands, six new ent-labdane glucosides, named microtropiosides A-F, were isolated together with one known acyclic sesquiterpene glucoside. The structures of the new compounds were elucidated by a combination of spectroscopic analyses, and their absolute configurations by application of the β-D-glucopyranosylation-induced shift-trend rule in the 13C NMR spectroscopy and the modified Mosher's method.
Keywords
Microtropis japonica
Celastraceae
ent-Labdane glucoside
Microtropioside
NDC
Medical sciences [ 490 ]
Language
eng
Resource Type journal article
Publisher
Pergamon-Elsevier Science LTD
Date of Issued 2010-04
Rights
Copyright (c) 2010 Elsevier Ltd
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0031-9422
[DOI] 10.1016/j.phytochem.2010.01.004
[NCID] AA00774558
[DOI] http://dx.doi.org/10.1016/j.phytochem.2010.01.004