Recyclable hydrogen storage system composed of ammonia and alkali metal hydride

International Journal of Hydrogen Energy Volume 34 Issue 24 Page 9760-9764 published_at 2009-12
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Title ( eng )
Recyclable hydrogen storage system composed of ammonia and alkali metal hydride
Creator
Yamamoto Hikaru
Hino Satoshi
Nakanishi Haruyuki
Source Title
International Journal of Hydrogen Energy
Volume 34
Issue 24
Start Page 9760
End Page 9764
Abstract
Ammonia (NH3) reacts with alkali metal hydrides MH (M = Li, Na, and K) in an exothermic reaction to release hydrogen (H-2) at room temperature, resulting that alkali metal amides (MNH2) which are formed as by-products. In this work, hydrogen desorption properties of these systems and the condition for the recycle from MNH2 back to MH were investigated systematically. For the hydrogen desorption reaction, the reactivities of MH with NH3 were better following the atomic number of M on the periodic table, Li < Na < K. It was confirmed that the hydrogen absorption reaction of all the systems proceeded under 0.5 MPa of H-2 flow condition below 300 degrees C.
Keywords
Hydrogen storage systems
Thermodynamic properties
Ammonia
Alkali metal hydrides
Mechanical milling
NDC
Physics [ 420 ]
Language
eng
Resource Type journal article
Publisher
Pergamin
Elsevier Science Ltd
Date of Issued 2009-12
Rights
Copyright (c) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0360-3199
[DOI] 10.1016/j.ijhydene.2009.10.034
[NCID] AA00680410
[DOI] http://dx.doi.org/10.1016/j.ijhydene.2009.10.034