Direct determination of the rate coefficient for the reaction of O(D-1) with OCS

Chemical Physics Letters Volume 483 Issue 1-3 Page 16-20 published_at 2009
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Title ( eng )
Direct determination of the rate coefficient for the reaction of O(D-1) with OCS
Creator
Orimi Kenichi
Watanabe Shinji
Source Title
Chemical Physics Letters
Volume 483
Issue 1-3
Start Page 16
End Page 20
Abstract
A gaseous mixture of O-3/OCS/He was irradiated at 266 nm with a pulsed laser, and vibrationally excited SO(X-3 Sigma, v = 8 and 19) generated in the reaction of O(D-1) with OCS was detected with the laser-induced fluorescence (LIF) via the B-3 Sigma -X-3 Sigma system. The apparent production rates of SO(v = 8) in the initial reaction time and their OCS pressure dependence have been measured, giving the absolute overall rate coefficient for the O(D-1) + OCS reaction.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Elsevier Science BV
Date of Issued 2009
Rights
Copyright (c) 2009 Elsevier B. V.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2009.10.033
[NCID] AA00602122
[DOI] http://dx.doi.org/10.1016/j.cplett.2009.10.033