Development of cyclic hydrazine and hydrazide type organocatalyst-mechanistic aspects of cyslic hydrazine/hydrazide-catalyzed diels-alder reactions

Heterocycles Volume 79 Page 851-863 published_at 2009
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Title ( eng )
Development of cyclic hydrazine and hydrazide type organocatalyst-mechanistic aspects of cyslic hydrazine/hydrazide-catalyzed diels-alder reactions
Creator
Hirata Ai
Source Title
Heterocycles
Volume 79
Start Page 851
End Page 863
Abstract
Some hydrazines and hydrazides were prepared and screened for their catalytic efficiencies in Diets-Alder reactions. H-1-NMR studies and ab initio calculations revealed that catalytic efficiencies of these catalysts are greatly dependent on the release of the catalysts from the Diels-Alder adducts.
Keywords
Organocatalyst
Diels-Alder Reaction
Hydrazine
Pyrazolidine
ydrazonium Ion
NDC
Medical sciences [ 490 ]
Language
eng
Resource Type journal article
Publisher
Pergamon-Elsevier Science Ltd
Date of Issued 2009
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0385-5414
[DOI] 10.3987/COM-08-S(D)54
[NCID] AA00663739
[DOI] http://dx.doi.org/10.3987/COM-08-S(D)54