Development of cyclic hydrazine and hydrazide type organocatalyst-mechanistic aspects of cyslic hydrazine/hydrazide-catalyzed diels-alder reactions
Heterocycles Volume 79
Page 851-863
published_at 2009
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Title ( eng ) |
Development of cyclic hydrazine and hydrazide type organocatalyst-mechanistic aspects of cyslic hydrazine/hydrazide-catalyzed diels-alder reactions
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Creator |
Hirata Ai
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Source Title |
Heterocycles
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Volume | 79 |
Start Page | 851 |
End Page | 863 |
Abstract |
Some hydrazines and hydrazides were prepared and screened for their catalytic efficiencies in Diets-Alder reactions. H-1-NMR studies and ab initio calculations revealed that catalytic efficiencies of these catalysts are greatly dependent on the release of the catalysts from the Diels-Alder adducts.
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Keywords |
Organocatalyst
Diels-Alder Reaction
Hydrazine
Pyrazolidine
ydrazonium Ion
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NDC |
Medical sciences [ 490 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
Pergamon-Elsevier Science Ltd
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Date of Issued | 2009 |
Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
[ISSN] 0385-5414
[DOI] 10.3987/COM-08-S(D)54
[NCID] AA00663739
[DOI] http://dx.doi.org/10.3987/COM-08-S(D)54
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