Fluorescence detected circular dichroism of a red-shifted exciton-coupling chromophore N,N'-carbonyl-bridged dipyrrinone derivative using an ellipsoidal device
Monatshefte für Chemie : Chemical Monthly Volume 139 Issue 6
Page 591-595
published_at 2008-06
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| File | |
| Title ( eng ) |
Fluorescence detected circular dichroism of a red-shifted exciton-coupling chromophore N,N'-carbonyl-bridged dipyrrinone derivative using an ellipsoidal device
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| Creator |
Boiadjiev Stefan E.
Lightner David A.
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| Source Title |
Monatshefte für Chemie : Chemical Monthly
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| Volume | 139 |
| Issue | 6 |
| Start Page | 591 |
| End Page | 595 |
| Abstract |
A fluorescent red-shifted exciton-coupling chromophore, N,N'-Carbonyl-bridged dipyrrinone, was subjected to fluorescence-detected CD (FDCD) measurements as a primitive structure-elucidating probe with trans-1,2-cyclohexanediol template in several solvents under various instrumental conditions. With the help of a JASCO ellipsoidal mirror device FDCD465, a chloroform solution achieved the sensitivity enhancement by 50 times of the transmission CD and 5 times of the conventional FDCD. All FDCD spectra were completely free from the polarization artifacts.
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| Keywords |
Circular Dichroism
Chromophore
Chirality
Configuration
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Springer
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| Date of Issued | 2008-06 |
| Rights |
Copyright (c) 2008 Springer-Verlag
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0026-9247
[DOI] 10.1007/s00706-007-0808-x
[NCID] AA00543624
[DOI] http://dx.doi.org/10.1007/s00706-007-0808-x
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