Synthesis and properties of coil-shaped 2,3-thienylene-ethynylene oligomers
Molecular Crystals and Liquid Crystals Volume 376 Issue 1
Page 153-158
published_at 2002
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| File | |
| Title ( eng ) |
Synthesis and properties of coil-shaped 2,3-thienylene-ethynylene oligomers
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| Creator |
Aso Yoshio
Obara Yuko
Okai Takashi
Nishiguchi Shoji
Otsubo Tetsuo
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| Source Title |
Molecular Crystals and Liquid Crystals
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| Volume | 376 |
| Issue | 1 |
| Start Page | 153 |
| End Page | 158 |
| Abstract |
A series of 2,3-thienylene-ethynylene oligomers have been synthesized by repeated application of the Pd-catalyzed coupling reaction of terminal alkynes and thienyl iodides as the key building steps. The analytical GPC molecular weights, much deflated relative to the actual molecular weights, strongly suggest a coil shape for the conformation of the oligomers in solution. Their electronic absorption and emission spectral features are discussed.
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| Keywords |
oligomers
thienylene-ethynylenes
electronic absorptions
emissions
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Taylor & Francis
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| Date of Issued | 2002 |
| Rights |
Copyright (c) 2002 Taylor & Francis. This is an electronic version of an article published in "Molecular Crystals and Liquid Crystals, Volume 376, Issue 1 2002, pages 153-158" Disability and Rehabilitation is available at: http://dx.doi.org/10.1080/10587250210795
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 1542-1406
[DOI] 10.1080/10587250210795
[NCID] AA11836169
[DOI] http://dx.doi.org/10.1080/10587250210795
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