Photo-induced convection of benzene solution of diphenylamine and carbon tetrabromide in strong magnetic fields

Molecular Physics Volume 104 Issue 10-11 Page 1703-1709 published_at 2006-05-20
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Title ( eng )
Photo-induced convection of benzene solution of diphenylamine and carbon tetrabromide in strong magnetic fields
Creator
Fumi Koyama
Tanimito Yoshifumi
Source Title
Molecular Physics
Volume 104
Issue 10-11
Start Page 1703
End Page 1709
Abstract
The influence of vertical magnetic fields on the photo-induced thermal convection of a benzene solution was studied qualitatively using a photo-imaging reaction of DPA-CBr 4 . By applying a magnetic field of -1200T 2 m -1 , the thermal convection of the photo-induced coloured solution is enhanced, whereas it is suppressed when a field of +1000T 2 m -1 is applied. The effect is explainable when the magnetic susceptibility of the coloured solution is smaller than that of the bulk solution. The behaviour of the coloured solution is dependent on both the solute concentration and irradiation time. These dependencies are interpreted in terms of the photon energy absorbed by the photo-irradiated solution.
NDC
Physics [ 420 ]
Language
eng
Resource Type journal article
Publisher
Taylor and Francis
Date of Issued 2006-05-20
Rights
Copyright (c) 2006 Taylor & Francis "This is an electronic version of an article published in Molecular Physics Vol.104 No.10-11 pp.1667-1674 2006. Molecular Physics is available online at http://dx.doi.org/10.1080/00268970500507778
Publish Type Author’s Original
Access Rights open access
Source Identifier
[NCID] AA00745902
[ISSN] 0026-8976
[DOI] 10.1080/00268970500507778
[DOI] http://dx.doi.org/10.1080/00268970500507778 isVersionOf