Influence of extended π-conjugation units on carrier mobilities in conducting polymers

Chemical Physics Letters Volume 420 Issue 4-6 Page 387-390 published_at 2006-03-21
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Title ( eng )
Influence of extended π-conjugation units on carrier mobilities in conducting polymers
Creator
Kim D-H.
Tsutitori Y.
Jiang X.
Patil R.
Kunai Atsutaka
Source Title
Chemical Physics Letters
Volume 420
Issue 4-6
Start Page 387
End Page 390
Abstract
Carrier mobilities in thin films of copolymers with repeat units consisting of oligothiophenes bridged by Si atoms are measured over a range of doping levels, where the numbers of thienylenes in the repeat unit are 7, 8, 10, 12, and 14. The mobilities for these polymer films increased with the increase in doping level and the mobility enhancement followed an increasing order of the π-conjugation length. The magnitude of the mobility increase for the Si polymer comprising 14 thiophene units reached ca. 104, implying that this π-conjugation length is almost sufficient to reproduce transport properties of polythiophenes.
NDC
Chemical technology [ 570 ]
Language
eng
Resource Type journal article
Publisher
Elsevier B.V.
Date of Issued 2006-03-21
Rights
Copyright (c) 2006 Elsevier B.V.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[NCID] AA00602122
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2006.01.009
[DOI] http://dx.doi.org/10.1016/j.cplett.2006.01.009 isVersionOf