Determination of absolute configuration of secondary alcohols using new chiral auxiliary and chemical shift calculation
Tetrahedron Letters Volume 47 Issue 10
Page 1519-1523
published_at 2006-03
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Title ( eng ) |
Determination of absolute configuration of secondary alcohols using new chiral auxiliary and chemical shift calculation
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Creator |
Iwamoto Hajime
Kobayashi Yuka
Kawatani Takefumi
Suzuki Masataka
Fukazawa Yoshimasa
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Source Title |
Tetrahedron Letters
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Volume | 47 |
Issue | 10 |
Start Page | 1519 |
End Page | 1523 |
Abstract |
A new chiral carboxylic acid 1 was synthesized for determination of absolute configuration of secondary alcohols. Several chiral alcohols were converted to esters with 1. Their experimental esterification shift changes were successfully reproduced by the chemical shift simulation method combined with molecular dynamic simulation.
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NDC |
Chemistry [ 430 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
Elsevier
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Date of Issued | 2006-03 |
Rights |
Copyright (c) 2006 Elsevier Ltd.
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Publish Type | Author’s Original |
Access Rights | open access |
Source Identifier |
[ISSN] 0040-4039
[DOI] 10.1016/j.tetlet.2006.01.011
[NCID] AA00861801
[DOI] http://dx.doi.org/10.1016/j.tetlet.2006.01.011
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