Determination of absolute configuration of secondary alcohols using new chiral auxiliary and chemical shift calculation

Tetrahedron Letters Volume 47 Issue 10 Page 1519-1523 published_at 2006-03
アクセス数 : 571
ダウンロード数 : 139

今月のアクセス数 : 2
今月のダウンロード数 : 1
File
TetrahedronLett_47_1519.pdf 384 KB 種類 : fulltext
Title ( eng )
Determination of absolute configuration of secondary alcohols using new chiral auxiliary and chemical shift calculation
Creator
Iwamoto Hajime
Kobayashi Yuka
Kawatani Takefumi
Suzuki Masataka
Fukazawa Yoshimasa
Source Title
Tetrahedron Letters
Volume 47
Issue 10
Start Page 1519
End Page 1523
Abstract
A new chiral carboxylic acid 1 was synthesized for determination of absolute configuration of secondary alcohols. Several chiral alcohols were converted to esters with 1. Their experimental esterification shift changes were successfully reproduced by the chemical shift simulation method combined with molecular dynamic simulation.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
Elsevier
Date of Issued 2006-03
Rights
Copyright (c) 2006 Elsevier Ltd.
Publish Type Author’s Original
Access Rights open access
Source Identifier
[ISSN] 0040-4039
[DOI] 10.1016/j.tetlet.2006.01.011
[NCID] AA00861801
[DOI] http://dx.doi.org/10.1016/j.tetlet.2006.01.011 isVersionOf