Direct Observation of Molecule-Substrate Antibonding States near the Fermi Level in Pd(110)-c(4x2)-Benzene
Physical Review Letters Volume 79 Issue 20
Page 3942-3945
published_at 1997-11-17
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| File | |
| Title ( eng ) |
Direct Observation of Molecule-Substrate Antibonding States near the Fermi Level in Pd(110)-c(4x2)-Benzene
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| Creator |
Yoshinobu Jun
Kawai Maki
Imamura Issei
Marumo Fumiyuki
Suzuki Ryochi
Ozaki Hiroyuki
Aoki Masaru
Masuda Shigeru
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| Source Title |
Physical Review Letters
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| Volume | 79 |
| Issue | 20 |
| Start Page | 3942 |
| End Page | 3945 |
| Abstract |
Evidence for a molecule-substrate hybridized state near the Fermi level EF is presented for Pd(110)- c(4x2)-benzene. Observed images of adsorbed benzene near EF by scanning tunneling microscopy consist of two elongated protrusions separated by a single nodal depression with C2 symmetry. The existence of a benzene derived state near EF is also observed by metastable atom electron spectroscopy, and it is assigned to the antibonding states between the 1e1g molecular orbital of benzene and the Pd 4d orbitals by ab initio molecular orbital calculations.
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| NDC |
Physics [ 420 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
American Physical Society
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| Date of Issued | 1997-11-17 |
| Rights |
Copyright (c) 1997 The American Physical Society
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| Publish Type | Version of Record |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.79.3942
[NCID] AA00773679
[DOI] http://dx.doi.org/10.1103/PhysRevLett.79.3942
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