Superconductivity in the silicon clathrate compound (Na,Ba)xSi46

Physical Review Letters Volume 74 Issue 8 Page 1427-1429 published_at 1995-02-20
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Title ( eng )
Superconductivity in the silicon clathrate compound (Na,Ba)xSi46
Creator
Kawaji Hitoshi
Horie Hiro-omi
Ishikawa Mitsuo
Source Title
Physical Review Letters
Volume 74
Issue 8
Start Page 1427
End Page 1429
Abstract
A new silicon clathrate compound containing barium, (Na,Ba)xSi46, becomes a type-II superconductor with a critical temperature (Tc) of about 4 K. In the compound, the silicon atoms are bonded tetrahedrally with about the same bond distances as in ordinary cubic diamond Si, but form 12- and 14-hedral cages which are linked by shared faces. The metal atoms are located in the center of the polyhedra. This is the first superconductor consisting of a Si sp3 covalent network.
NDC
Physics [ 420 ]
Language
eng
Resource Type journal article
Publisher
American Physical Society
Date of Issued 1995-02-20
Rights
Copyright (c) 1995 American Physical Society
Publish Type Version of Record
Access Rights open access
Source Identifier
[NCID] AA00773679
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.74.1427
[DOI] http://dx.doi.org/10.1103/PhysRevLett.74.1427